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Rayon, see Regenerated cellulose Reaction injection molding, 132 Reaction volume, 296 Reactions of polymers, see Polymer reaction Reactivation chain polymerization, 165 166 Reactive center, 7 9 Reactive polymer, 760. See also Functional polymer; Polymer catalyst; Polymer reagent; Polymer substrate Reactive surfactant, 367 Reactive telechelic oligomer, 155 Reactivity: functional group, 41 44 monomer, see Monomer reactivity ratio polymer effect of crosslinking, 732 effect of crystallinity, 731 effect of solubility, 731 732 electrostatic effect, 733 735 hydrophobic interaction, 735 736 isolation of functional groups, 730 local concentration of functional group, 730 731 neighboring group effect, 735 other effects, 736 737 steric effect, 732 733 yield, 730 Reactivity ratio, see Monomer reactivity ratio Recombinant DNA technology, 180 181 Redox grafting, 756 Redox polymerization, 216 221 Re face, 642 644 Refractive index, 209 Regenerated cellulose, 746 Regioselective reaction, 203, 646 Regulator, 250 Reinforcing agent, 96, 742 Repeat(ing) unit, 2, 50 51 Resist, 219, 744 Resole polymer, 120 124 Retardation, see Inhibition Retarder, 256 Retro Diels-Alder, 155 Reverse addition fragmentation transfer, 320 321, 368 369 Reversible polymerization: copolymerization, 515 518 radical chain polymerization, 279 281 ring-opening polymerization, 562 565 step polymerization, 65 69 Reversible termination, 314 Reversible transfer, 314 Rhoplex, 308

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RIM, see Reaction injection molding Ring-opening copolymerization, 600 606 Ring-opening metathesis polymerization, 589 592, 631 632, 683, 759 Ring-opening polymerization: activated monomer, 547 block copolymer, 604 605 of N-carboxy-a-amino acid anhydride, 578 581 copolymerization, 600 606 cyclic acetal, 559 562 cyclic amide (lactam), 569 577 cyclic amine (imine), 586 587 cyclic carbonate, cyclic ester (lactone), 548 569, 581 586 cyclic ether, 548 569 cycloalkane, 594 cycloalkene, 589 592 cycloalkyne, 591 cyclosiloxane, 595 597 epoxide, 548 569 general characteristics, 545 548 miscellaneous monomers, 594 595, 599 600 nitrogen heterocyclics, 586 588 oxygen heterocyclics, 592 594 phosphonitrillic chloride, 597 599 stereochemistry, 707 708 sulfur heterocyclics, 588 589 uses, 568 569, 581, 591, 597 zwitterion, 587 589, 605 606 See also Anionic ring-opening polymerization; Cationic ring-opening polymerization; Stereoselective polymerization Ring polymer, 159 162, 525 527 Ring size, 70 72, 545 546 ROMP, see Ring-opening metathesis polymerization Room temperature vulcanization silicone rubber, 133 134 ROP, see Ring-opening polymerization Rotating sector method, 264 267 RTV, see Room temperature vulcanization silicone rubber Rubber, see Elastomer Rubber hydrochloride, 749 Ryton, 151 SAN, see Styrene-acrylonitrile copolymer Saran wrap, 306 Saturated hydrocarbon rubber, 749 750 SBR rubber, see Styrene-1,3-butadiene rubber Scavenger, 767 Schotten-Baumann reaction, 90 92

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2-98

On the Banks Islands in the Southwest Pacific a very highly developed credit and currency system in terms of strings of shells was closely connected with a system of men s clubs or secret societies This was more ceremonial than economic Admission to the clubs cost a large quantity of shell money, and promotion in rank cost even more Shell money was little needed and little used for everyday life, but a poor man required shells to make a start in life by joining a society The standard rate of interest for borrowing shells was 100% for any period If a man had insufficient shells to join a society, he could loan what he had to others and in time the interest would provide him with his initiation fee.

FIGURE C-3

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If free interchange occurs, the molecular weight distribution will be the Flory distribution described by Eqs. 2-86 and 2-89. Free interchange coresponds to all interunit linkages in all polymer molecules having equal probabilities of interchange. This is analogous to the concept of functional group reactivity independent of molecular size as applied to the interchange reaction. It is apparent that the presence of interchange during a polymerization will not affect the size distribution from that expected for the random polymerization. The Flory or most probable distribution is also that expected for the random scission of the interunit linkages of polymer chains, for example, in the hydrolysis of cellulose. 2-7d Alternate Approaches for Molecular-Weight Distribution

A number of treatments other than that by Flory have been given for the molecular weight distributions in linear step polymerizations [Burchard, 1979; Durand and Bruneau, 1979a,b]. However, a knowledge of the average properties (M n , M w , and PDI) is often suf cient for many practical purposes. Macosko and Miller [1976] developed a useful statistical approach for obtaining the average properties without the need to calculate the molecular weight distributions. This approach will be described for a polymerization system composed of A A, B and B0 0 where A groups can react with B groups and with B0 groups [Ozizmir and B, B Odian, 1980]. To keep the system as simple as possible, the molecular weights of the three structural units are taken as equal (and denoted by Mo ) and the initial system contains equimolar amounts of B and B0 0 monomers where the total moles of A is equal to the B B A sum of B and B0 0 . B B

The unusual feature of this system was that a man was entitled to impose a loan on an unwilling borrower who had to repay with interest under threat of severe penalties Nor is this the only case we find of coerced debtors The situation was not unlike the gift economies of Homeric and medieval times, when a gift had to be requited by a larger gift Kings gave abundantly to other kings and to their own nobles, but such gifts were often costly to the recipients Even today social customs at times have encouraged retributive giving: for example, at Christmas time, birthdays, and weddings The giver sometimes may contemplate a return with an agio (11) 5 On Vancouver Island, in Canada, not long ago, blankets had taken the place of furs and wampum as the monetary unit of the Kwakiutl.

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vb.net ocr read text from pdf

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vb.net ocr read text from pdf

vb.net ocr read text from pdf

vb.net ocr read text from pdf

vb.net ocr read text from pdf

vb.net ocr read text from pdf

vb.net ocr read text from pdf

vb.net ocr read text from pdf

vb.net ocr read text from pdf

vb.net ocr read text from pdf

vb.net ocr read text from pdf

vb.net ocr read text from pdf