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The probability of this process, p, decreases exponentially with the total-to-free volume ratio, v/v{: p=exp(-v/vf) Equations (2.6.16) and (2.6.17) can be rearranged to the form: p =exp[-B/(r-r0)] (2.6.18) (2.6.17). The common disadvantage of both the free volume and onfiguration entropy models is their quasi-thermodynamic approach. The ion transport is better described on a microscopic level in terms of ion size, charge, and interactions with other ions and the host matrix. This makes a basis of the percolation theory, which describes formally the ion conductor as a random mixture of conductive islands (concentration c) interconnected by an essentially non-conductive matrix. (The mentioned formalism is applicable not only for ion conductors, but also for any insulator/conductor mixtures.) 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