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Automated HS sampling is preferable for quantitative analysis, because the thermal equilibration time vial pressurization, and injection volume can be precisely controlled, thus reducing the variability of analytical results. Stein and Narang used static HS GC equipped with a photoionization detector to determine benzene and other VOCs in egg whites, whole eggs, and egg yolks. Benzene was quanti ed on the basis of a forti ed egg standard or a series of egg standards (23). Page et al. conducted an interlaboratory study in which three laboratories analyzed bottled drinking water for benzene and other VOCs by using static HS with either GC/MS or GC/FID; 182 samples were analyzed. GCs were equipped with either an on-column or split-splitless injector and a cryogenically cooled oven. Benzene found in the samples was quanti ed by using external standards. The overall RSDR for benzene was determined to be 14% (26). 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